Beilstein J. Org. Chem.2017,13, 1222–1229, doi:10.3762/bjoc.13.121
-anhydro-α-L-galactopyranose unit (naturally present in the agarose structure) to all glycamines synthesized, constituting an amino-substituted C-threofuranoside moiety, which is closely related to (+)-muscarine.
Keywords: amino sugar; 3,6-anhydro-α-L-galactopyranose; polysaccharide (agar); protecting
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Graphical Abstract
Scheme 1:
Overview of the hydrolysis–reductive amination procedure to produce primary glycamine 3 and byprodu...